Not all file metadata fields are shown

Correct, Explorer has some metadata columns that Opus doesn't have, and vice versa.

If the data you are interested in is available to VBScript or JScript then a script add-in could be written to add a column to Opus that displays it. The Office apps tend to have good automation support, so it's possible that approach would be the way to go, although I don't have experience with automating Outlook.

Column: Word Count for Microsoft Word documents is a similar script add-in that provides a column showing metadata extracted through Word's automation support.