Free Download Manager opens Explorer instead of Opus

It all depends how they're opening the folder. There's an official API function call that apps can use, and if they do then Opus will intercept it. Unfortunately not a lot of developers know about that function, so they end up doing it one of several other ways, only some of which can be intercepted.

We'll have a look and see but it's possible there's nothing we can do from our end, the developers of the other app would need to make a change to enable this to work properly.