thanks for the screenshots, but i would like to perform both rename-actions with one button...
so i wrote two rename operations in the script editor, first catches all files which includes e.g. "s02e11"... this part does it's job like it should...
but my main problem is that i don't know, how to write an regexp which catches all files, except those who begin with e.g. "s02e11"...
No, Opus doesn't handle lookaheads, it's a very basic RegEx. Leo can tell you the flavor of it I believe, but the bottom line is what you see in the help file about RegEx is what Opus can do with it.
I have to admit I'm back in the weeds again when it comes to understanding just what it is you're trying to do here, but hopefully you're getting it worked out.
You're better off using a rename script if you want to do anything involving conditional logic.
You can use anything supported by ActiveScript, e.g. VBScript, Javascript, Perl... There's a few threads you'll find useful in the rename scripting forum if you want to go that route.