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Do you mean the old Control Panel from Windows 7 and earlier (and still there in 11 but somewhat hidden/deprecated), or the newer Settings?
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How is the shortcut added to the desktop? There isn't one by default.
I tried adding the Control Panel shortcut to the desktop via Personalization > Themes > Desktop Icon Settings, and it works OK for me with Opus set to replace Explorer.
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What do you have set under Preferences / Launching Opus / Explorer Replacement?
(The "recommended" setting there is usually best, and should completely ignore Control Panel.)
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Have you installed any other file managers that can replace Explorer? We've had similar threads which turned out to be a conflict between their registry settings and ours.
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Make sure Compatibility Mode is not turned on for any of the Opus executables, as that can mess up Explorer Replacement: Windows Compatibility Settings / Wrong DPI / Installer misdetects OS
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